MATERIAL SAFETY DATA SHEETS

MAXI-MIZER DIESEL TREATMENT

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SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

 

PRODUCT NAME:    Maxi-Mizer Diesel Treatment                          TRADE NAME:  Maxi-Mizer Diesel Treatment

LABEL NAME:          Same                                                                    DESCRIPTION:  Flammable Liquid.  Petroleum Distillates N.O.S.

MANUFACTURER:    Eagle Marketing, Inc.                                        PRODUCT USE:  Fuel Treatment    

                  2412 Sequoia Park                                             DATE PREPARED:  12-29-08

                                  Yukon, OK 73099                                                 PREPARED BY:  Anita McNeil

 

EMERGENCY PHONE:  Domestic North America 405-354-1027

                                        \ \

                                         

 

NFPA 704M/HMIS RATING:   1/2 HEALTH            2/2 FLAMMABILITY              0/0 REACTIVITY                     0 OTHER

0 = Insignificant    1 = Slight                2 = Moderate                        3 = High                  4 = Extreme 

      

 

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

 

Our hazard evaluation has identified the following chemical Ingredient(s) as hazardous under OSHA’S Hazard Communication Rule 29 CFR 1910.1200.  Consult Section 15 for the nature of the hazard(s).                                                                                                                                                                                                                        

INGREDIENT(S):                                      CAS NO.                                 APPROXIMATE %

                                                                                  

Dicyclopentadienryl Iron                    102-54-2                                 1 – 5

Light aromatic naphtha                      64742-95-6                             70 – 100

 

SECTION 3: HAZARDS IDENTIFICATION

                                                                                                                                                                                                                               

EMERGENCY OVERVIEW:

CAUTION:  Combustible. May cause irritaiton to skin and eyes.  Prolonged inhalation of vapor may be harmful.  Avoid contact with skin, eyes and clothing. Avoid prolonged or repeated breating of vapor.   Use with adequate ventilation.  Do not take internally.  Keep away from heat and open flame.  Keep container closed when not is use.

 

Empty containers  may contain residual product.  Do not reuse container unless properly reconditioned.

     

PRIMARY ROUTE(S) OF EXPOSURE:  Eyes, Skin,  Inhalation

 

       EYES:               Can cause moderate irritation.

       SKIN:                Can cause mild irritation.                                 

       INHALATION:  Prolonged inhalation of vapor or mist may be harmful.

             

SYMPTOMS OF EXPOSURE:

ACUTE:  Inhalation of high concentrations of light aromatic naptha can cause nausea, dizziness, vomiting, stupor or unconsciousness.

      

CHRONIC:  Prolonged skin contact with heavy aromatic naptha can cause defatting of skin, resulting in irritation and dermatitis. 

 

AGGRAVATIONI OF EXISTING CONDITIONS:  A review of available data does not identify any worsening of existing conditions. 

     

 

SECTION 4:  FIRST AID INFORMATION

 

EYES: Immediately flush with water for at least 15 minutes while holding eyelids open.  Call a physician at once.

            

SKIN:  Wash thoroughly with soap and rinse with water.  Call a physician.

     

INGESTION:  DO NOT INDUCE VOMITING.  Give 2 glasses of water.  Call a physician. 

     

INHALATION:  Remove to fresh air.  Treat symptoms.  Call a physician.

 

NOTES TO PHYSICIANS OR FIRST AID PROVIDERS:  Based on the individual reactions of the patient, the physician’s judgement should be used to control symptons and clicical condition.

 

CAUTION:  If unconscious, or having trouble breathing or in convulsions, do not induce vomiting or give water.   

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SECTION 5: FIRE-FIGHTING MEASURES

 

FLASH POINT:  116°-127° F (PMCC)    ASTM D-93

         

AUTOIGNITION TEMPERATURE:  Greater than 495° F (ASTM D2155-66)

 

LEL:  1%

                                           

EXTINGUISHING MEDIA:  Based on NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires.  Use water to cool containers exposed to fire.  For large fires, use water spray or fog, thoroughly drenching the burning material.       

     

UNUSUAL FIRE AND EXPLOSION HAZARD:  Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture.  

     

 

SECTION 6: ACCIDENTAL RELEASE MEASURES

 

IN CASE OF TRANSPORATION ACCIDENTS.  CALL THE FOLLOWING TELEPHONE NUMBER, Domestic North America (800)424-9300, International, Call + 1 703-527-3887.    Chemtec Customer#:231418.

 

SPILL CONTROL AND RECOVERY:

 

Small liquid spills:  Contain with absorbent material, such as clay, soil, or any other commercially available absorbent.  Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal.  Refer to CERCLA in Section 15.

 

Large liquid spills:  Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal.  Refer to CERCLA in Section 15.

 

Large indoor spills:  Evacuate employees and ventilate area.   Those responsible for control and recovery should wear the protective equipment specified in Section 8.

 

Keep the spill away from heat, sparks, flames, and welding operations.  Ventilate area and evacuate employees from exposure if the airborne concentration exceeds the TLV.  Refer to Section 15. 

 

 

SECTION 7:  HANDLING AND STORAGE

 

HANDLING AND STORAGE:  Keep container closed when not is use.

      

 

SECTION 8:  EXPOSURE CONTROLS/PERSONAL PROTECTION

 

 RESPIRATORY PROTECTION:  Respiratory protections is not normally needed since the volatility and toxicity are low.  If significant mists are generated use either a chemical cartridge respirator with a dus/mist prefilter or supplied air. 

 

For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation,  a positive pressure, self-contained breating apparatus is recommended.

 

VENTILATION :  General ventilation is recommended.    

    

PROTECTIVE EQUIPMENT:  Use impermeable gloves and chemical splash goggles when attatching feeding equipment, doing maintenance or handling product.  Examples of impermeable gloves available on the market are neoprene, nitrile, natural rubber, and vitron (compatibility studies have not been preformed.)

 

The availability of any eye wash fountain and safety shower is recommended.

 

 If clothing is contaminated, remove and thoroughly wash the affected area.  Launder contaminated clothing before reuse.

 

HUMAN EXPOSURE CHARACTERIZATION:  Based on Eagle’s recommended product application and our recommended personal protective equipment the potential for human exposure is:  MODERATE.      

 

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SECTION 9:  PHYSICAL AND CHEMICAL PROPERTIES

 

COLOR:                                  Clear amber                                         FORM:  Liquid      

DENSITY:                                6.9 – 7.2 lbs/gallon                                              

SPECIFIC GRAVITY:               0.83 @ 60°F                                           ASTM D-1298

FLASH POINT:                        116 - 127°F (PMCC)                               ASTM D-93

VAPOR PRESSURE:               3 mm Hg @ 68°F                                   ASTM D-323

 

NOTE:      These physical properties are typical values for this product.                 

 

SECTION 10: STABILITY AND REACTIVITY

 

INCOMPATIBILITY:  Avoid contact with strong oxidizers (e.g. Chorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates)  which can generate heat, fires, explosions and the release of toxic fumes.                                                                                                                                        

      

THERMAL DECOMPOSITION PRODUCTS:   In the event of combustion CO, CO2. may be formed.  Do not breathe smoke or fumes.  Wear suitable protective equipment.     

 

SECTION 11:  TOXICOLOGICAL INFORMATION

 

TOXICOLOGICAL STUDIES:  No toxicity studies have been conducted on this product.    

     

 

SECTION 12:  ECOLOGICAL INFORMATION

 

ECOLOGICAL INFORMATION:  If released into the environment, see CERCLA in Section 15.            

 

SECTION 13:  DISPOSAL  CONSIDERATIONS

 

WASTE DISPOSAL METHOD:  If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the resource Conservation and Recovery Act (RCRA) 40CFR261.  Hazardous Waste D001.  In addition, this product may contain trace levels of benzene.  Before desposal, the product should be analyzed to determine if it meets the hazardous waste classification of D018 (Toxicity Characteristic Leaching Procedure [TCLP] Test).

 

As a hazardous liquid waste.  It must be solidified with stabilizing agents (such as sand, fly ash, or cement)  so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal Facility).  A hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations.  

   

     

SECTION 14:   TRANSPORT INFORMATION

 

PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY PACKAGING, PROPERTIES, AND MODE OF TRANSPORTATION.  THIS PRODUCT IS REGULATED IN THE U.S. ONLY WHEN SHIPPED IN CONTAINERS EXCEEDING 110 GALLONS OR 882 POUNDS CAPACITY OR WHEN THE PACKAGE EXCEEDS THE REPORTABLE QUANTITY.  TYPICAL PROPER SHIPPING NAMES FOR THE PRODUCT ARE:

ALL TRANSPORTATION MODES:        PETROLEUM DISTILLATES, N.O.S.

 

BULK TRUCK SHIPMENTS:                   FLAMMABLE LIQUID, N.O.S.

    

       UN/ID NO.:                                        UN 1268

       HAZARD CLASS – PRIMARY:        3 COMBUSTIBLE LIQUID (NON BULK TRUCK TRANSPORT ONLY)– All other modes

                                                                3 Flammable Liquid               

       PACKING GROUP:                           III   

       IMDG PAGE NO.:                             3375

       IATA PACKAING INSTRUCTION:   CARGO:310

       IATA CARGO AIRCRAFT LIMIT:   220 L (MAX NET QUANTITY PER PACKAGE)

 

       FLASH POINT:                 116°F  46.6°C

       TECHNICAL NAME (S):                  AROMATIC HYDROCARGONS

        RQ LBS (PER PACKAGE):             NONE

        RQ COMPONENT (S):                    NONE

 

SECTION 15: REGULATORY INFORMATION

 

The following regulatons apply to this product.

 

FEDERAL REGULATiONS:

 

OSHA HAZARD COMMUNICATIONS RULE 29 CFR 1910.1200:

Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below.

 

Light aromatic naphta = Combustible, irritant

 

Dicyclopenatadienly iron = irritant

 

Dicyclopentadienly iron = TWA 10mg/3   ACGIH/TLV

 

Dicyclopentadienly iron = TWA 10 mg/m3   OSHA/PEL

 

CERCLA/SUPERFUND 40 CRF 117, 302:

Notification of spills of this product is not required.

 

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986

(TITLE III) SECTIONS 302, 311, 312, AND 313:

 

SECTION 302 – EXTREMELY HAZARDOUS SUBSTANCES 940 CFR 355):

This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance.

 

SECTIONS 311 AND 312 – MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous.  The product should be reported under the following EPA hazard categories:

 

XX Immediate (acute) health hazard

---- Delayed (chronic) health hazard

XX Fire Hazard

---- Sudden release of pressure hazard

---- Reactive hazard

 

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.  The current threshoilds are:  500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazzrdous substances and 10,000 pounds for all other hazardous chemicals.

 

SECTION 313 – LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain ingredients on the List of Toxic Chemicals.

 

RESOURCE CONSERVATION AND RECOVERY ACT, AND RECOVERY ACT, (RCRA), 40 CFR 261 SUBPART C & D:

Consult Section 14 for RCRA classification.

 

FEDERAL WATER POLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 formerly Section 307, 40 CFR 116/formerly Section 311:

None of the ingredients are specifically listed.

 

CLEAN AIR ACT, Section 111 (40 CFR 60), Section 112 (40 CFR 61, 1990 Amendments), Section 611 (40 CFR 82, CLASS I and II Ozone depleting substances):

This product does not contain ingredients covered by the Clean Air Act.

 

STATE REGULATIONS:        

 

CALIFORNIA PROPOSITION 65:

Substances known to the State of California to cause cancer are present in this product.

 

MICHIGAN CRITICAL MATERIALS:    

                This product does not contain ingredients liated on the Michigan Critical Materials Register.

 

STATE RIGHT TO KNOW LAWS:

Regulated in those states using the TLV for ferrocene as a criteria for listing.

 

INTERNATIONAL REGULATIONS:

This product is WHMIS controlled product under The House of Commons of Canada Bill C-70 (Class D2B).  The product

contains following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological

properties, to contain the following hazardous ingredients (s):

 

Chemical Name                                    CAS#                                      % Concentration Range

 

Dicylopentadienly Iron                        102-54-2                                                 1-5

Light aromatic naphtha                      64742-95-6                                             70-100  

 

SECTION 16:  OTHER INFORMATION

 

OTHER  INFORMATION:  Empty drums must not be reused without cleaning.  Residual vapor in empty drums may ignite/detonate if sparks or welding are in the vicinity and must be avoided.

 

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SECTION 17:   RISK CHARACTERIZATION

 

Due to our commitment of Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product.  Based on our recommended use of this product, we have characterized the product’s general risk.  This informaiotn should provide assistance for your own risk management practices.  We have evaluated our product’s risk as follows:

 

·          The human risk is:  MODERATE.

·          The environmental risk is:  MODERATE.   

 

Any use inconsistent with Eagle’s recommendations may affect our risk characterization.  Our sales representatives will assist you tp determine if your product application is consistent with our recommendations.  Together we can implement on appropriate risk management process.

 

This product material safety date sheet provides health and safety information.  The product is to be used in applications consistent with our product literature.  Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.  For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations.

 

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SECTION 18 REFERENCES        _____________________________________________________________________________________                                                                                                                                                                               

 

Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, Ohio.

 

Hazardous Substances Data Bank, National Library of Medicine, Bethesdam Maryland (CD-ROM version), Micromedes, Inc., Englewood, Colorado.

 

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva:  World Health Organization, Intenational Agency for Research on Cancer. 

 

Integrated Risk Information System, U.S. Enviromental Protection Agency, Washington, DC (CD-ROM Version), Micromedex, Inc., Englewood, Colorado.

 

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

 

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA).

 

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, Ohio (CD-ROM version), MIcromedex, Inc., Englewood, Colorado.

 

Shepard’s Catalogue of Teratogenic Agents (CD-ROM version), Micromedex, Inc. Englewood, Colorado

 

Suspect Chemicals Sourcebook (a guide to industrial chemicals covered under major regulatory and advisory program), Roytech Publications (a Division pf Ariel Corporation), Bethesda, MD

 

The Teratogen Information System, University of Washington, Seattle, WA (CD-ROM version), Micromedex, Inc., Englewood, Colorado.